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Automated Materials Discovery Platform Realized: Scanning Probe Microscopy of Combinatorial Libraries

2024-12-24 · Yu Liu, Rohit Pant, Ichiro Takeuchi, R. Jackson Spurling, Jon-Paul Maria, Maxim Ziatdinov, Sergei V. Kalinin

Combinatorial libraries are a powerful approach for exploring the evolution of physical properties across binary and ternary cross-sections in multicomponent phase diagrams. Although the synthesis of these libraries has been developed since the 1960s and expedited with advanced laboratory automation, the broader application of combinatorial libraries relies on fast, reliable measurements of concentration-dependent structures and functionalities. Scanning Probe Microscopies (SPM), including piezoresponse force microscopy (PFM), offer significant potential for quantitative, functionally relevant combi-library readouts. Here we demonstrate the implementation of fully automated SPM to explore the evolution of ferroelectric properties in combinatorial libraries, focusing on Sm-doped BiFeO3 and ZnxMg1-xO systems. We also present and compare Gaussian Process-based Bayesian Optimization models for fully automated exploration, emphasizing local reproducibility (effective noise) as an essential factor in optimal experiment workflows. Automated SPM, when coupled with upstream synthesis controls, plays a pivotal role in bridging materials synthesis and characterization.

📄 PDF Abstract BibTeX arXiv:2412.18067

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Bayesian Optimization

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