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Constrained Diffusion for Accelerated Structure Relaxation of Inorganic Solids with Point Defects

2026-02-22 · Jingyi Cui, Jacob K. Christopher, Ankita Biswas, Prasanna V. Balachandran, Ferdinando Fioretto arxiv

Point defects affect material properties by altering electronic states and modifying local bonding environments. However, high-throughput first-principles simulations of point defects are costly due to large simulation cells and complex energy landscapes. To this end, we propose a generative framework for simulating point defects, overcoming the limits of costly first-principles simulators. By leveraging a primal-dual algorithm, we introduce a constraint-aware diffusion model which outperforms existing constrained diffusion approaches in this domain. Across six defect configuration settings for Bi2Te3, the proposed approach provides state-of-the-art performance generating physically grounded structures.

📄 PDF Abstract BibTeX arXiv:2602.19153

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